Hot off the press: accepted manuscript in Faraday Discussions!

FARADAY_Forthcoming-publcation-198x300We are very happy to announce that the manuscript Gold nanotriangles decorated with superparamagnetic iron oxide nanoparticles: a compositional and microstructural study (J.A. Hachtela, S. Yuc , A.R. Lupini, S.T. Pantelidesa, M. Gich, A. Laromaine, A. Roig, DOI: 10.1039/C6FD00028B) has been accepted by the Faraday Discussions journal.

The manuscript will be presented and discussed at a forthcoming Faraday Discussions meeting, this next summer. During the meeting, all delegates will be able to contribute to the debate, which will be included in the final volume. This will be a great opportunity to discuss the formation mechanism of the magnetic gold nanotriangles with some experts on this field. 

The combination of iron oxide and gold in a single nanoparticle results in both magnetic and plasmonic properties that can stimulate novel applications in bio-sensing, medical imaging, or therapeutics. Microwave heating method allows the fabrication of multi-component, multi-functional nanostructures by promoting selective heating at desired sites. Recently, we reported a microwave-assisted polyol route yielding gold nanotriangles decorated with iron oxide nanoparticles (1). Here, we present an in-depth microstructural and compositional characterization of the system by using scanning transmission electron microscopy (STEM) and electron energy loss (EELS) spectroscopy. A method to remove the iron oxide nanoparticles from the gold nanocrystals and some insights on crystal nucleation and growth mechanisms are also provided.

gold-nanoT

Figure: (a) Schematic representation of the synthesis route. (b) HRTEM image of a Au NH-SPIONs and a Au NT-SPIONs. Characterization of the heterostructures: (c) UV-Vis-NIR spectra. (d) Hydrodynamic diameter of the Au-SPIONS measured by DLS. (e) Magnetization curve up to 6 T at 5K.

(1) Magnetic gold nanotriangles by microwave polyol synthesis (S.M. Yu, J.A. Hachtel, M.F. Chisholm, S.T. Pantelides, A. Laromaine, A. Roig; Nanoscale 2015, 7, 14039-14046. DOI: 10.1039/C5NR03113C). 

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