Hot off the press: First paper from Miquel and Pol!

Schematic representation of the two-step microwave-assisted synthesis of Au/TiO2 nanostructures.

New publication from the N&N group in collaboration with the Universitat Politècnica de Catalunya!

 

Congratulations to all the authors of the manuscript and especially to Miquel Torras (Ph.D. student at the N&N group) and Pol Sallés (previous researcher at the N&N group) for the first publication of their careers! The paper “Fast and Simple Microwave Synthesis of TiO2/Au Nanoparticles for Gas-Phase Photocatalytic Hydrogen Generation” has been published on April 12th 2018 at the open access journal Frontiers in Chemistry.

 

Abstract: The fabrication of small anatase titanium dioxide (TiO2) nanoparticles (NPs) attached to larger anisotropic gold (Au) morphologies by a very fast and simple two-step microwave-assisted synthesis is presented. The TiO2/Au NPs are synthesized using polyvinylpyrrolidone (PVP) as reducing, capping and stabilizing agent through a polyol approach. To optimize the contact between the titania and the gold and facilitate electron transfer, the PVP is removed by calcination at mild temperatures. The nanocatalysts activity is then evaluated in the photocatalytic production of hydrogen from water/ethanol mixtures in gas-phase at ambient temperature. A maximum value of 5.3 mmol·g−1cat⋅gcat-1·h−1 (7.4 mmol·g−1TiO2⋅gTiO2-1·h−1) of hydrogen is recorded for the system with larger gold particles at an optimum calcination temperature of 450°C. Herein we demonstrate that TiO2-based photocatalysts with high Au loading and large Au particle size (≈50 nm) NPs have photocatalytic activity.

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